NAVRACHANA UNIVERSITY

Ferrocene-linked thymine/uracil conjugates: base pairing directed self-assembly and supramolecular packing

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dc.contributor.author Patwa, Amit N.
dc.contributor.author Gupta, Susmita
dc.contributor.author Gonnade, Rajesh G.
dc.contributor.author Kumar, Vaijayanti A.
dc.contributor.author Bhadbhade, Mohan M.
dc.contributor.author Ganesh, Krishna N.
dc.date.accessioned 2019-06-14T06:56:21Z
dc.date.available 2019-06-14T06:56:21Z
dc.date.issued 2008-01-23
dc.identifier.issn 0022-3263 (P-ISSN)
dc.identifier.issn 1520-6904 (E-ISSN)
dc.identifier.uri http://27.109.7.66:8080/xmlui/handle/123456789/587
dc.description The Journal of Organic Chemistry, Vol-73, Issue-4, 2008, p. 1508-1515 en_US
dc.description.abstract Ferrocene-linked bis(nucleobase) (1a-c) and chimeric nucleobase (1d) conjugates have been synthesized from mono- and bis(hydroxybutyl)ferrocene 6 via Mitsunobu reaction as the key step. X-ray crystallographic studies of ferrocene bis(nucleobase) conjugates reveal two-dimensional supramolecular organizations of backbones through self-assembled Watson-Crick and reverse Watson-Crick type pairs. Ferrocene-bis(thymine) conjugate self-assembles by reverse Watson-Crick pairing, while the corresponding bis(uracil) conjugate self-assembles by alternating WC and reverse WC type pairing. Such continuous assemblies are not seen in monosubstituted ferrocene nucleobase conjugates which form only planar sheets. The results are interesting from the point of understanding and engineering supramolecular assemblies through rational design of base pairing patterns. en_US
dc.language.iso en_US en_US
dc.publisher American Chemical Society en_US
dc.subject Ferrocene en_US
dc.subject Nucleoside en_US
dc.subject Self-assembly en_US
dc.subject Supramolecules en_US
dc.subject Single crystal structure en_US
dc.subject Hydrogen bonding en_US
dc.title Ferrocene-linked thymine/uracil conjugates: base pairing directed self-assembly and supramolecular packing en_US
dc.type Article en_US


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